  {"id":102949,"date":"2019-09-10T14:51:25","date_gmt":"2019-09-11T00:51:25","guid":{"rendered":"https:\/\/www.hawaii.edu\/news\/?p=102949"},"modified":"2019-09-11T13:57:34","modified_gmt":"2019-09-11T23:57:34","slug":"new-pathway-for-carbon-chemistry","status":"publish","type":"post","link":"https:\/\/www.hawaii.edu\/news\/2019\/09\/10\/new-pathway-for-carbon-chemistry\/","title":{"rendered":"Scientists reveal new pathway for carbon chemistry to evolve in space"},"content":{"rendered":"<span class=\"span-reading-time rt-reading-time\" style=\"display: block;\"><span class=\"rt-label rt-prefix\">Reading time: <\/span> <span class=\"rt-time\"> 2<\/span> <span class=\"rt-label rt-postfix\">minutes<\/span><\/span><figure id=\"attachment_102963\" aria-describedby=\"caption-attachment-102963\" style=\"width: 300px\" class=\"wp-caption alignright\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.hawaii.edu\/news\/wp-content\/uploads\/2019\/09\/image2.jpg\" alt=\"machines\" width=\"300\" height=\"400\" class=\"size-full wp-image-102963\" srcset=\"https:\/\/www.hawaii.edu\/news\/wp-content\/uploads\/2019\/09\/image2.jpg 300w, https:\/\/www.hawaii.edu\/news\/wp-content\/uploads\/2019\/09\/image2-98x130.jpg 98w, https:\/\/www.hawaii.edu\/news\/wp-content\/uploads\/2019\/09\/image2-225x300.jpg 225w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><figcaption id=\"caption-attachment-102963\" class=\"wp-caption-text\">Experimental setup at the Chemical Dynamics Beamline of the Advanced Light Source (<abbr>ALS<\/abbr>) incorporating the chemical micro reactor exploited in the present studies.<\/figcaption><\/figure>\n<p>A team of scientists led by <a href=\"http:\/\/manoa.hawaii.edu\">University of <span aria-label=\"Hawaii\">Âé¶¹´«Ã½<\/span> at M\u0101noa<\/a> Professor <strong>Ralf Kaiser<\/strong> has discovered a new possible pathway toward forming carbon structures in space using a specialized chemical exploration technique at the Department of Energy\u2019s <a href=\"https:\/\/www.lbl.gov\/\">Lawrence Berkeley National Laboratory<\/a> (Berkeley Lab\u2019s <a href=\"https:\/\/als.lbl.gov\/\">Advanced Light Source<\/a>). The team also included computational chemists from Florida International University. <\/p>\n<p><a href=\"https:\/\/www.nature.com\/articles\/s41467-019-11652-5\">In the study, published in <em>Nature Communications<\/em><\/a>, researchers produced a ringed, carbon-containing molecule by combining two highly reactive chemical species that are called free radicals because they contain unpaired electrons. <\/p>\n<p>The team\u2019s research has now identified several key avenues by which ringed molecules known as polycyclic aromatic hydrocarbons, or <abbr title=\"polycyclic aromatic hydrocarbons\">PAHs<\/abbr>, can form in space. <\/p>\n<p><abbr>PAHs<\/abbr>&#8212;which also occur on Earth in emissions and soot from the combustion of fossil fuels&#8212;could provide clues to the formation of life\u2019s chemistry in space as precursors to interstellar nanoparticles.<\/p>\n<p>The study ultimately showed how these chemical processes could lead to the development of carbon-containing graphene-type <abbr>PAHs<abbr> and <abbr title=\"two dimensional\">2D<\/abbr> nanostructures. Graphene is a one-dimensional layer of fused hexagons consisting of carbon atoms. <\/p>\n<p>&ldquo;This is something that people have tried to measure experimentally at high temperatures for decades but have not done successfully before,&rdquo; said Musahid Ahmed, a scientist in Berkeley Lab\u2019s Chemical Sciences Division. &ldquo; We believe this is yet another pathway that can give rise to PAHs.&rdquo;<\/p>\n<p>Kaiser added, &ldquo;The present experiment clearly provides scientific evidence that reactions between radicals at elevated temperatures do form aromatic molecules such as naphthalene.&rdquo;<\/p>\n<p>The latest study is part of an ongoing effort of the <span aria-label=\"Hawaii\">Âé¶¹´«Ã½<\/span>-Berkeley-Florida team to retrace the chemical steps leading to the formation of complex carbon-containing molecules in deep space up to all-carbon-containing soccer-shaped buckyball molecules.<\/p>\n<p><a href=\"https:\/\/newscenter.lbl.gov\/2019\/09\/03\/radical-wrinkle-complex-carbon-molecules-in-space\/\">Read the full news release for more on the discovery.<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Researchers produced a ringed, carbon-containing molecule by combining two highly reactive chemical species that are called free radicals because they contain unpaired electrons.<\/p>\n","protected":false},"author":16,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[30],"tags":[251,308,1363,158,174,9],"class_list":["post-102949","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-research","tag-chemistry","tag-college-of-natural-sciences","tag-manoa-research","tag-publication","tag-space","tag-uh-manoa","entry","has-media"],"aioseo_notices":[],"jetpack_featured_media_url":"","_links":{"self":[{"href":"https:\/\/www.hawaii.edu\/news\/wp-json\/wp\/v2\/posts\/102949","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.hawaii.edu\/news\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.hawaii.edu\/news\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.hawaii.edu\/news\/wp-json\/wp\/v2\/users\/16"}],"replies":[{"embeddable":true,"href":"https:\/\/www.hawaii.edu\/news\/wp-json\/wp\/v2\/comments?post=102949"}],"version-history":[{"count":21,"href":"https:\/\/www.hawaii.edu\/news\/wp-json\/wp\/v2\/posts\/102949\/revisions"}],"predecessor-version":[{"id":102988,"href":"https:\/\/www.hawaii.edu\/news\/wp-json\/wp\/v2\/posts\/102949\/revisions\/102988"}],"wp:attachment":[{"href":"https:\/\/www.hawaii.edu\/news\/wp-json\/wp\/v2\/media?parent=102949"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.hawaii.edu\/news\/wp-json\/wp\/v2\/categories?post=102949"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.hawaii.edu\/news\/wp-json\/wp\/v2\/tags?post=102949"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}